For decades researchers have investigated a theoretical means to double the power output of solar cells–by making use of so-called “hot electrons.” Now researchers at Boston College have provided new experimental evidence that the theory will work. They built solar cells that get a power boost from high-energy photons. This boost, the researchers say, is the result of extracting hot electrons.
The results are a step toward solar cells that break conventional efficiency limits. Because of the way ordinary solar cells work, they can, in theory, convert at most about 35 percent of the energy in sunlight into electricity, wasting the rest as heat. Making use of hot electrons could result in efficiencies as high as 67 percent, says Matthew Beard, a senior scientist at the National Renewable Energy Laboratory in Golden, CO, who was not involved in the current work. Doubling the efficiency of solar cells could cut the cost of solar power in half.
A Swiss company says it has developed rechargeable zinc-air batteries that can store three times the energy of lithium ion batteries, by volume, while costing only half as much. ReVolt, of Staefa, Switzerland, plans to sell small “button cell” batteries for hearing aids starting next year and to incorporate its technology into ever larger batteries, introducing cell-phone and electric bicycle batteries in the next few years. It is also starting to develop large-format batteries for electric vehicles.
This graphic illustrates the multilayered structure of a ReVolt rechargeable zinc-air battery. From top to bottom: the battery cover, which lets in air; a porous air electrode; the interface between electrodes; the zinc electrode; the casing. Credit: ReVolt
The battery design is based on technology developed at SINTEF, a research institute in Trondheim, Norway. ReVolt was founded to bring it to market and so far has raised 24 million euros in investment. James McDougall, the company’s CEO, says that the technology overcomes the main problem with zinc-air rechargeable batteries–that they typically stop working after relatively few charges. If the technology can be scaled up, zinc-air batteries could make electric vehicles more practical by lowering their costs and increasing their range.
Unlike conventional batteries, which contain all the reactants needed to generate electricity, zinc-air batteries rely on oxygen from the atmosphere to generate current. In the late 1980s they were considered one of the most promising battery technologies because of their high theoretical energy-storage capacity, says Gary Henriksen, manager of the electrochemical energy storage department at Argonne National Laboratory in Illinois. The battery chemistry is also relatively safe because it doesn’t require volatile materials, so zinc-air batteries are not prone to catching fire like lithium-ion batteries.
